Periphery-Fused Chiral A2B-Type Subporphyrin

Partons in the chiral periphery of the nucleon

We introduce transverse densities in the study of parton dynamics in the proton’s peripheral region. We calculate these densities using chiral perturbation theory (χPT) and parametrize the long distance structure of the nucleon in a model independent framework in which we identify chiral (b ∼ O(1/Mπ)) and molecular (b ∼ O(M 2 N/(M 3 π))) parametrical regions. Through the light cone formulation ...

Intramolecular electron transfer reactions in meso-(4-nitrophenyl)-substituted subporphyrins.

A2B-type meso-(4-nitrophenyl)-substituted subporphyrins have been synthesized and shown to undergo very fast photoinduced intramolecular charge separation (CS) and charge recombination (CR) between the subporphyrin core and the meso-4-nitrophenyl group in CH2Cl2 as probed by femtosecond time-resolved transient absorption spectroscopy. Red-shifted emissions were detected from charge-separated st...

Novel chiral "calixsalen" macrocycle and chiral robson-type macrocyclic complexes.

A family of novel chiral "calixsalen" Schiff base macrocycles R,R-H(3)L4, R,R-H(3)L5, containing three chiral diamino moieties were synthesized by an efficient self-assembly and characterized by (1)H and (13)C NMR, mass spectrometry, and X-ray diffraction. The systematic synthesis, structure, and coordination properties of the [2 + 2] and [3 + 3] Robson-type Schiff base macrocyclic mono-, di-, ...

Synthesis of meso-substituted subphthalocyanine-subporphyrin hybrids: boron subtribenzodiazaporphyrins.

The first syntheses of hybrid structures that lie between subphthalocyanines and subporphyrins are reported. The versatile single-step synthetic method uses a preformed aminoisoindolene to provide the bridging methine unit and its substituent while trialkoxyborates simultaneously act as Lewis acid, template, and provider of the apical substituent. The selection of each component therefore allow...

Adenosine A2B receptors.